Microelectrochemistry study of metal-hydride battery materials cycling behavior of LaNi3.55Mn0.4Al0.3Co0.75 compared with LaNi5 and its mono-substituted derivatives
Identifieur interne : 000303 ( France/Analysis ); précédent : 000302; suivant : 000304Microelectrochemistry study of metal-hydride battery materials cycling behavior of LaNi3.55Mn0.4Al0.3Co0.75 compared with LaNi5 and its mono-substituted derivatives
Auteurs : A. Merzouki [Algérie] ; C. Cachet-Vivier [France] ; V. Vivier [France] ; J.-Y. Nedelec [France] ; L. T. Yu [France] ; N. Haddaoui [Algérie] ; J.-M. Joubert [France] ; A. Percheron-Guegan [France]Source :
- Journal of power sources [ 0378-7753 ] ; 2002.
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Abstract
LaNi5 intermetallic-hydride forming compound and several metal-substituted derivatives have been compared in terms of cycling behavior observed by means of the cavity microelectrode (CME) at high scan rates (50 mVs-1). LaNi3.55Mn0.4Al0.3Co0.75 was found to have a stable behavior over 1000 cycles, whereas, the capacity of LaNi5 decreases after only 200 cycles The performances for the mono-substituted compounds are intermediate. The rechargeability decreases according to the following order: LaNi4.6Mn0.4 > LaNi4.7Al0.3>LaNi4.25Co0.75 > LaNi5. This study demonstrates the capability of the CME to check numerous battery materials in a very short period of time, which allows to bring out the effect due to the corrosion of the material.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Microelectrochemistry study of metal-hydride battery materials cycling behavior of LaNi<sub>3.55</sub>Mn<sub>0.4</sub>Al<sub>0.3</sub>Co<sub>0.75</sub> compared with LaNi<sub>5</sub> and its mono-substituted derivatives</title><author><name sortKey="Merzouki, A" sort="Merzouki, A" uniqKey="Merzouki A" first="A." last="Merzouki">A. Merzouki</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Hauts Polymères, Dépt. Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université F. Abbas</s1><s2>Sétif 19000</s2><s3>DZA</s3><sZ>1 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Algérie</country><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Cachet Vivier, C" sort="Cachet Vivier, C" uniqKey="Cachet Vivier C" first="C." last="Cachet-Vivier">C. 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Abbas</s1><s2>Sétif 19000</s2><s3>DZA</s3><sZ>1 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Algérie</country><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Joubert, J M" sort="Joubert, J M" uniqKey="Joubert J" first="J.-M." last="Joubert">J.-M. Joubert</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Percheron Guegan, A" sort="Percheron Guegan, A" uniqKey="Percheron Guegan A" first="A." last="Percheron-Guegan">A. Percheron-Guegan</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">02-0503885</idno><date when="2002">2002</date><idno type="stanalyst">PASCAL 02-0503885 INIST</idno><idno type="RBID">Pascal:02-0503885</idno><idno type="wicri:Area/PascalFrancis/Corpus">000389</idno><idno type="wicri:Area/PascalFrancis/Curation">000052</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000389</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000389</idno><idno type="wicri:doubleKey">0378-7753:2002:Merzouki A:microelectrochemistry:study:of</idno><idno type="wicri:Area/Main/Merge">000A46</idno><idno type="wicri:Area/Main/Curation">000A23</idno><idno type="wicri:Area/Main/Exploration">000A23</idno><idno type="wicri:Area/France/Extraction">000303</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Microelectrochemistry study of metal-hydride battery materials cycling behavior of LaNi<sub>3.55</sub>Mn<sub>0.4</sub>Al<sub>0.3</sub>Co<sub>0.75</sub> compared with LaNi<sub>5</sub> and its mono-substituted derivatives</title><author><name sortKey="Merzouki, A" sort="Merzouki, A" uniqKey="Merzouki A" first="A." last="Merzouki">A. Merzouki</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Hauts Polymères, Dépt. Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université F. Abbas</s1><s2>Sétif 19000</s2><s3>DZA</s3><sZ>1 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Algérie</country><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Cachet Vivier, C" sort="Cachet Vivier, C" uniqKey="Cachet Vivier C" first="C." last="Cachet-Vivier">C. Cachet-Vivier</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie Catalyse et Synthèse Organique - UMR 7582 CNRS-Université Paris 12, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Vivier, V" sort="Vivier, V" uniqKey="Vivier V" first="V." last="Vivier">V. Vivier</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie Catalyse et Synthèse Organique - UMR 7582 CNRS-Université Paris 12, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Nedelec, J Y" sort="Nedelec, J Y" uniqKey="Nedelec J" first="J.-Y." last="Nedelec">J.-Y. Nedelec</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie Catalyse et Synthèse Organique - UMR 7582 CNRS-Université Paris 12, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Yu, L T" sort="Yu, L T" uniqKey="Yu L" first="L. T." last="Yu">L. T. Yu</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Laboratoire d'Electrochimie Catalyse et Synthèse Organique - UMR 7582 CNRS-Université Paris 12, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Haddaoui, N" sort="Haddaoui, N" uniqKey="Haddaoui N" first="N." last="Haddaoui">N. Haddaoui</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Hauts Polymères, Dépt. Génie des Procédés, Faculté des Sciences de l'Ingénieur, Université F. Abbas</s1><s2>Sétif 19000</s2><s3>DZA</s3><sZ>1 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Algérie</country><wicri:noRegion>Sétif 19000</wicri:noRegion></affiliation></author><author><name sortKey="Joubert, J M" sort="Joubert, J M" uniqKey="Joubert J" first="J.-M." last="Joubert">J.-M. Joubert</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author><author><name sortKey="Percheron Guegan, A" sort="Percheron Guegan, A" uniqKey="Percheron Guegan A" first="A." last="Percheron-Guegan">A. Percheron-Guegan</name><affiliation wicri:level="3"><inist:fA14 i1="03"><s1>Laboratoire de Chimie Métallurgique des Terres Rares, CNRS, 2-8 rue H. Dunant</s1><s2>94320 Thiais</s2><s3>FRA</s3><sZ>7 aut.</sZ><sZ>8 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Île-de-France</region><settlement type="city">Thiais</settlement></placeName></affiliation></author></analytic><series><title level="j" type="main">Journal of power sources</title><title level="j" type="abbreviated">J. power sources</title><idno type="ISSN">0378-7753</idno><imprint><date when="2002">2002</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Journal of power sources</title><title level="j" type="abbreviated">J. power sources</title><idno type="ISSN">0378-7753</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Corrosion</term><term>Discharge charge cycle</term><term>Electric batteries</term><term>Intermetallic compound</term><term>Lanthanum</term><term>Metal Hydrides</term><term>Microelectrode</term><term>Nickel</term><term>Performance</term><term>Secondary cell</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Accumulateur électrochimique</term><term>Batterie électrique</term><term>Métal Hydrure</term><term>Composé intermétallique</term><term>Lanthane</term><term>Nickel</term><term>Cycle charge décharge</term><term>Microélectrode</term><term>Performance</term><term>Corrosion</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Nickel</term><term>Corrosion</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">LaNi<sub>5</sub> intermetallic-hydride forming compound and several metal-substituted derivatives have been compared in terms of cycling behavior observed by means of the cavity microelectrode (CME) at high scan rates (50 mVs<sup>-1</sup>). LaNi<sub>3.55</sub>Mn<sub>0.4</sub>Al<sub>0.3</sub>Co<sub>0.75</sub> was found to have a stable behavior over 1000 cycles, whereas, the capacity of LaNi<sub>5</sub> decreases after only 200 cycles The performances for the mono-substituted compounds are intermediate. The rechargeability decreases according to the following order: LaNi<sub>4.6</sub>Mn<sub>0.4</sub> > LaNi<sub>4.7</sub>Al<sub>0.3</sub>>LaNi<sub>4.25</sub>Co<sub>0.75</sub> > LaNi<sub>5</sub>. This study demonstrates the capability of the CME to check numerous battery materials in a very short period of time, which allows to bring out the effect due to the corrosion of the material.</div></front></TEI><affiliations><list><country><li>Algérie</li><li>France</li></country><region><li>Île-de-France</li></region><settlement><li>Thiais</li></settlement></list><tree><country name="Algérie"><noRegion><name sortKey="Merzouki, A" sort="Merzouki, A" uniqKey="Merzouki A" first="A." last="Merzouki">A. Merzouki</name></noRegion><name sortKey="Haddaoui, N" sort="Haddaoui, N" uniqKey="Haddaoui N" first="N." last="Haddaoui">N. Haddaoui</name></country><country name="France"><region name="Île-de-France"><name sortKey="Cachet Vivier, C" sort="Cachet Vivier, C" uniqKey="Cachet Vivier C" first="C." last="Cachet-Vivier">C. Cachet-Vivier</name></region><name sortKey="Joubert, J M" sort="Joubert, J M" uniqKey="Joubert J" first="J.-M." last="Joubert">J.-M. Joubert</name><name sortKey="Nedelec, J Y" sort="Nedelec, J Y" uniqKey="Nedelec J" first="J.-Y." last="Nedelec">J.-Y. Nedelec</name><name sortKey="Percheron Guegan, A" sort="Percheron Guegan, A" uniqKey="Percheron Guegan A" first="A." last="Percheron-Guegan">A. Percheron-Guegan</name><name sortKey="Vivier, V" sort="Vivier, V" uniqKey="Vivier V" first="V." last="Vivier">V. Vivier</name><name sortKey="Yu, L T" sort="Yu, L T" uniqKey="Yu L" first="L. T." last="Yu">L. T. 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